Decarboxylative Trifluoromethylation of Aliphatic Carboxylic Acids
نویسندگان
چکیده
منابع مشابه
Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis.
The direct conversion of aliphatic carboxylic acids to the corresponding alkyl fluorides has been achieved via visible light-promoted photoredox catalysis. This operationally simple, redox-neutral fluorination method is amenable to a wide variety of carboxylic acids. Photon-induced oxidation of carboxylates leads to the formation of carboxyl radicals, which upon rapid CO2-extrusion and F(•) tra...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2018
ISSN: 0002-7863,1520-5126
DOI: 10.1021/jacs.8b02650